Mixture interactions and operating conditions determine vapor–liquid separation, not pure-component boiling points alone.
Engineering models need empirical property parameters; this is not a quantitative prediction for a particular wash.
Relative volatility and azeotropes explain why a boiling-point sequence is an incomplete account of congener behavior. Apply the principle without inventing a whiskey-specific recovery curve.
Original synthesis from SRC-637. Developing, not an independently validated whiskey-specific claim. See linked literature note and located chapter evidence.
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Atomic idea
Mixture interactions and operating conditions determine vapor–liquid separation, not pure-component boiling points alone.
Reasoning
Relative volatility and azeotropes explain why a boiling-point sequence is an incomplete account of congener behavior. Apply the principle without inventing a whiskey-specific recovery curve.
Counterpoints
Engineering models need empirical property parameters; this is not a quantitative prediction for a particular wash.
Provenance and connections
Distillation: Fundamentals and Principles — full-volume analysis
SRC-637 ch2 — Mixture behavior requires more than pure boiling points
Developing interpretation. Not established as an independently tested whiskey-specific claim.